Delocalized fermions in underdoped cuprate superconductors

Low-temperature heat transport was used to investigate the ground state of high-purity single crystals of the lightly doped cuprate YBa2Cu3O6.33. Samples were measured with doping concentrations on either side of the superconducting phase boundary. We report the observation of delocalized fermionic excitations at zero energy in the nonsuperconducting state, which shows that the ground state of underdoped cuprates is a thermal metal. Its low-energy spectrum appears to be similar to that of the d-wave superconductor, i.e., nodal. The insulating ground state observed in underdoped La2-xSrxCuO4 is attributed to the competing spin-density-wave order.     

Delayed fracture in porous media

The fracture of porous media subjected to a constant load is studied. Contrary to homogeneous solids in which fracture usually happens instantaneously at a well-defined breaking strength, the fracture of a porous medium can occur with a delay, allowing us to quantify the average lifetime of the unbroken material. We show that the average fracture probability, a key property for risk analysis in civil engineering, is given by the probability of crack nucleation. The nucleation process can be understood qualitatively by calculating the activation energy for crack nucleation, taking into account the porosity of the medium.     

Surface crystallization of amorphous solid water

We demonstrate that the crystallization of thin, supported amorphous solid water layers is initiated at the water surface. This is concluded from the observation of sequential crystallization of amorphous water at the surface, in the bulk, and at the water-support interface. A surface nucleation model quantitatively reproduces the observed transformation kinetics at the three sites.     

Long-range critical wetting: observation of a critical end point

Alkanes deposited on aqueous substrates exhibit two different types of wetting behavior: alternatively to the usual first-order wetting transition, a sequential-wetting scenario of a long-range critical wetting transition preceded by a first-order thin-thick transition may be observed. Here, we present the first successful experimental attempt to locate the transition point between the standard first-order wetting and the long-range critical wetting: a critical end point, observed in a mixture of pentane and hexane which is deposited on an aqueous solution of glucose. Furthermore, we present the first direct measurement of the contact angle in the intermediate wetting state (frustrated-complete wetting) in the sequential-wetting scenario of hexane on brine and compare to theoretical predictions.     

Rod-climbing effect in Newtonian fluids

When a rotating rod is brought into a polymer melt or concentrated polymer solution, the meniscus climbs the rod. This spectacular rod climbing is due to the normal stresses present in the polymer fluid and is thus a purely non-Newtonian effect. A similar rod climbing of an interface between two fluids has therefore been taken as a signature that one of the fluids exhibits normal stress effects. We show here, however, that the effect can occur with simple Newtonian fluids: it occurs when a Taylor-Couette instability happens in the less viscous of the two liquids but not in the more viscous one.     

Vibrational spectroscopic investigation of the phase diagram of a biomimetic lipid monolayer

The phase behavior of a biomimetic monolayer consisting of diphospholipid molecules on water is investigated using vibrational sum-frequency generation and fluorescence microscopy. In addition to the transition from the-molecularly disordered-liquid phase to the highly ordered and oriented con-densed phase, a novel, extremely sharp transition is observed at low compression, which is attributed to the uncurling of the hydrophobic alkane chains upon compression.     

Coupling between flow and structure for a lamellar surfactant phase

The flow-structure relation of lamellar phases is studied using rheometry and cross-polarized microscopy under flow. The equilibrium phases show different defects. Low salinities lead to very viscous, "onion" phases, whereas at high salinity, a low viscosity plane lamellar phase is found. Under shear, the latter shows a sudden transition to a viscoelastic gel, with a texture and viscosity very similar to that of the onions. Gelation occurs after a certain delay time, increasing rapidly with salinity, by the nucleation of onions. This allows one to relate the delay time to the defect energy.     

Phonon screening in high-temperature superconductors

In good conductors optical phonons are usually screened, and therefore not observed. However, sharp features due to infrared-active modes in the copper-oxygen planes are observed in the optical conductivity of Pr1.85Ce0.15CuO4 and YBa2Cu3O6.95. Oscillator strengths indicate that the screening of these modes is poor or totally absent. These materials are compared with eta-Mo4O11, in which lattice modes appear suddenly below the charge-density wave transition. It is proposed that poor screening in the cuprates originates from fluctuating charge inhomogeneities in the copper-oxygen planes.